Hanna Instruments offers a wide variety of pH electrodes that are designed for many different applications. The type of glass used for sensing pH, bulb shape, body material, type of junction, type of reference and electrolyte used are just some of the design considerations.
The HI10530 is a digital electrode that has low temperature (LT) glass, conical bulb, glass body, triple ceramic junction and is refillable with 3.5M KCl.
The built-in microchip stores sensor type, serial number and calibration information including date, time, offset, slope, probe condition and buffers used. This information is automatically retrieved by edge® once the electrode is plugged in. The ability to transfer information allows for hot swapping of probes without having to recalibrate. All pH measurements are performed within the electrode and transferred digitally to the meter. This overcomes any noise issues associated with the traditional high impedance analog measuring system. Electrical noise can be generated from a built in temperature sensor and while working in a humid environment.
Spherical Glass Tip
The spherical shaped tip design allows for a wide area of contact with the measured sample. This permits a faster electrode response with a higher degree of stability. The glass sensing tip on the HI10430 uses Hanna’s high temperature (HT) glass formulation that has a resistance of approximately 400 megaohms. The high impedance makes the HI10430 ideal for aggressive chemical applications and high temperature applications. Conventional glass formulations suffer from a greatly reduced lifespans at high temperatures relative to high temperature glass.
The glass body is ideal for laboratory use. The glass is resistant to many harsh chemicals and is easily cleaned. The glass body also allows for a fast transfer of heat to the internal reference electrolyte. The mV generated by the reference cell is temperature dependent. The faster the equilibrium the steadier the reference potential.
Triple Ceramic Junction
The triple ceramic junction allows a faster flow rate of electrolyte from the reference into the solution. A standard pH electrode will use a single ceramic junction that allows for 15 to 20 µL/hour of electrolyte to flow; the HI10530 has three ceramic junctions, providing for 40 to 50 µL/hour of electrolyte to flow. This high flow rate provides faster electrode response and more stable measurement in viscous solutions or samples of low conductivity, such as pure water, where a long stabilization time is often observed.
Double Junction Reference
A double junction electrode has an internal compartment surrounding the reference wire. Silver ions are present in the electrolyte of the internal compartment, which houses the Ag/AgCl reference wire; the electrolyte outside this compartment is silver free. The double junction design means that virtually no silver from the electrode enters the sample. This design allows measurement in applications where silver ions in the sample are undesirable or for samples that contains sulfides that can cause the silver to precipitate and clog the junction. Clogging of the junction will result in drifty and erratic readings.
The HI10530 is a refillable probe. Since it is a double junction pH electrode the fill solution is the HI7082 3.5M KCl. This solution does not contain any silver as with single junction electrode.
3.5 mm Connector
The HI10530 uses a 3.5 mm connector that makes attaching and removing the probe simple and easy. This type of connector is proprietary to meters that use digital electrodes.
SINGLE JUNCTION VS DOUBLE JUNCTION
Conventional electrodes are normally single junction. As depicted, these electrodes have only a single junction between the internal refernce wire and the external solution. Under adverse conditions, such as high pressure, high temperature, highly acidic or alkaline solutions, the positive flow of the electrolyte through the junction is often reversed resulting in the ingress of sample solution into the reference compartment. If this is left unchecked, the reference electrode can become contaminated, leading to complete electrode failure. Another potential problem with single junction electrodes is the clogging of the junction due to silver chloride (AgCl) precipitation. Silver can be easily precipitate in samples that contain Tris buffer, sulfides or heavy metals. When the electrolyte solution makes contact with the sample, some AgCl will precipitate on the external face of the junction. The result is drifty readings obtained from the sensor.
Hanna’s double junction system, as the name implies, has two junctions, only one of which is in contact with the sample as shown in the figure. Under adverse conditions, the same tendency of sample ingress is evident. However, as the reference electrode system is separated physically from the intermediate electrolyte area, the contamination of the electrode is minimized. The likelihood of clogging of the junction is also reduced with a double junction electrode since the outer reference cell uses a fill solution that is “silver-free”. Since there is no silver present, there is no precipitate forming to clog the junction.